rendered competent by them to distinguish between primary and secondary results, he proceeds to establish the doctrine of 'Definite Electro-chemical Decomposition.'

Into the same circuit he introduced his voltameter, which consisted of a graduated tube filled with acidulated water and provided with platinum plates for the decomposition of the water, and also a cell containing chloride of tin. Experiments already referred to had taught him that this substance, though an insulator when solid, is a conductor when fused, the passage of the current being always accompanied by the decomposition of the chloride. He wished to ascertain what relation this decomposition bore to that of the water in his voltameter.

Completing his circuit, he permitted the current to continue until 'a reasonable quantity of gas' was collected in the voltameter. The circuit was then broken, and the quantity of tin liberated compared with the quantity of gas. The weight of the former was 3·2 grains, that of the latter 0·49742 of a grain. Oxygen, as you know, unites with hydrogen in the proportion of 8 to 1, to form water. Calling the equivalent, or as it is sometimes called, the atomic weight of hydrogen 1, that of oxygen is 8; that of water is consequently 8 + 1 or 9. Now if the quantity of water decomposed in Faraday's experiment be represented by the number 9, or in other words by the equivalent of water, then the quantity of tin liberated from the fused chloride is found by an easy calculation to be 57·9, which is almost exactly the chemical equivalent of tin. Thus both the water and the chloride were broken up in proportions expressed by their respective equivalents. The amount of electric force which wrenched asunder the constituents of the molecule of water was competent, and neither more nor less than competent, to wrench asunder the constituents of the molecules of the chloride of tin. The fact is typical. With the indications of his voltameter he compared the decompositions of other substances, both singly and in series. He submitted his conclusions to numberless tests. He purposely introduced secondary actions. He endeavoured to hamper the fulfilment of those laws which it was the intense desire of his mind to see established. But from all these difficulties emerged the golden truth, that under every variety of circumstances the decompositions of the voltaic current are as definite in their character as those chemical combinations which gave birth to the atomic theory. This law of Electro-chemical Decomposition ranks, in point of importance, with that of Definite Combining Proportions in chemistry.


  By PanEris using Melati.

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